Sada Cruzeiro suffered their first loss after claiming victories during the first two days of the competition.
Pavel Moroz was the main offensive force for Lokomotiv with 26 points, including five serving aces, while Anton Astashenkov (13), Lukas Divis (12) and Artem Volvich (11) also reached double digits in the scores.
Cuban-born Yoandy Leal and Wallace Souza topped Sada Cruzeiro with 20 and 19 points, respectively, and Douglas Cordeiro tallied 11 points.
The winners committed 35 unforced errors compared to 33 by the defeated side. Lokomotiv had the top hand in blocks (10-7) and also in aces (9-6).
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